Poly[octaaquadi-μ-phosphato-trinickel(II)]
نویسندگان
چکیده
In the title compound, [Ni(3)(PO(4))(2)(H(2)O)(8)](n), which was synthesized hydro-thermally, all the Ni atoms are located in slightly distorted octa-hedral coordination environments. Two phosphate groups and two Ni atoms share a centrosymmetric four-membered ring and an eight-membered ring such that the four-membered ring is inside the eight-membered ring. The eight-membered rings are connected with the other Ni atoms (lying on centres of symmetry) through phosphate anions, generating a one-dimensional chain structure. Adjacent chains are connected through hydrogen bonds, forming a three-dimensional network.
منابع مشابه
Poly[octaaquadi-μ-phosphato-trinickel(II)]. Corrigendum
A correction is made to the name of the first author in Shouwen, Wang, Gao, Wen & Zhou [Acta Cryst. (2008), E64, m259].[This corrects the article DOI: 10.1107/S1600536807067050.].
متن کاملcatena-Poly[1,2,2-trimethylcyclopentane-1,3-diammonium [aluminate(III)-μ-(hydrogen phosphato)-μ-phosphato]]
In the title compound, {(C(8)H(20)N(2))[Al(HPO(4))(PO(4))]}(n), the Al(III) atom is coordinated by four O atoms from two HPO(4) (2-) and two PO(4) (3-) groups in a distorted tetra-hedral geometry. Each AlO(4) unit shares four O atoms with four adjacent PO(4) units, leading to an anionic chain along [100]. The negative charge of the chain is compensated by doubly protonated camphoric amine catio...
متن کاملBis(methanol-1κO)tetra-μ-pyridazine-1:2κ4 N:N′;2:3κ4 N:N′-di-μ-thiocyanato-1:2κ2 N:N;2:3κ2 N:N-tetrathiocyanato-1κ2 N,3κ2 N-trinickel(II) methanol tetrasolvate
Reaction of an excess nickel(II) thio-cyanate with pyridazine leads to single crystals of the title compound, [Ni(3)(NCS)(6)(N(2)C(4)H(4))(4)(CH(3)OH)(2)]·4CH(3)OH. The crystal structure consists of trimeric discrete complexes, in which two Ni(II) cations are coordinated by two terminal and one μ-1,1 bridging thio-cyanato anions, one methanol mol-ecule and two bridging pyridazine ligands, where...
متن کاملPoly[[μ-bis(4-nitrophenyl) phosphato-κ2 O,O′]sodium]
The title compound, [Na(C12H8N2O8P)], consists of one Na(+) cation and one bis-(p-nitro-phen-yl)phosphate anion with a considerable distortion of the phosphate tetra-hedron due to the presence of two P-O ester bonds. The anion bridges five Na(+) cations whereby each cation is chelated by the nitro O atoms of one anion and bonded via a nitro O atom and phosphate O atoms to four other anions. Thi...
متن کاملcatena-Poly[[(ethanol-κO)sodium(I)]-di-μ-aqua-[(rac-2′-hydroxy-1,1′-binaphthyl-2-yl phosphato-κO)sodium]-tri-μ-aqua]
The asymmetric unit of the polymeric title compound, [Na(2)(C(20)H(13)O(5)P)(C(2)H(6)O)(H(2)O)(5)](n), consists of two Na(I) ions, one 2'-hydr-oxy-1,1'-binaphthyl-2-yl phosphate anion, one ethanol ligand and five water molecules of crysallization. Each Na(I) ion has a distorted octa-hedral coordination geometry. The phosphate anion coordinates to one Na(I) ion and the ethanol mol-ecule coordina...
متن کامل